Electrolysis of Molten NaCl - GG Resource

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Sunday, August 7, 2022

Electrolysis of Molten NaCl

At temperature of 8010C, Sodium Chloride (NaCl) melts and separate into Sodium and Chloride ions.

Ions Formed After Dissociation

Compound

Anion

Cation

NaCl

Cl-

Na+

Migration of Ion

Cathode

Anode

Na+

Cl-

Discharge

Based on the ions present, Na+ will be discharged at the Cathode and Cl- will be discharged at the anode.

At cathode:  Na+  +  2e ------> Na(s)

At Anode:  Cl-  ------> Cl2(g) + 2e

Overall equation for reaction

Na+  +  Cl-   ------> Na(s)  +  Cl(g)

Product

Sodium will be produced at cathode and Chlorine gas will be produced at anode

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